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	<title>Sequence Omega &#187; lithium carbonate</title>
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	<description>Fundamentally Different</description>
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		<title>Lithium Math &#8211; Quick Update</title>
		<link>http://www.sequence-omega.net/2010/05/27/lithium-math-quick-update/</link>
		<comments>http://www.sequence-omega.net/2010/05/27/lithium-math-quick-update/#comments</comments>
		<pubDate>Fri, 28 May 2010 06:36:19 +0000</pubDate>
		<dc:creator>Anthony</dc:creator>
				<category><![CDATA[Batteries]]></category>
		<category><![CDATA[lithium]]></category>
		<category><![CDATA[lithium carbonate]]></category>
		<category><![CDATA[peak lithium]]></category>

		<guid isPermaLink="false">http://www.sequence-omega.net/?p=1062</guid>
		<description><![CDATA[An Autoblog Green article today had an interesting tidbit of information. The Nissan Leaf has a 24kWh battery, that we knew. But Nissan also said the battery has about 9lbs (4.08kg) of Lithium in it. Presumably this is elemental lithium, and that is equivalent to 21.75 kg of Lithium Carbonate (LCE) which is how Lithium comes [...]]]></description>
			<content:encoded><![CDATA[<p>An <a href="http://green.autoblog.com/2010/05/27/details-on-nissan-leaf-battery-pack-including-how-recharging-sp/">Autoblog Green article</a> today had an interesting tidbit of information. The Nissan Leaf has a 24kWh battery, that we knew. But Nissan also said the battery has about 9lbs (4.08kg) of Lithium in it. Presumably this is elemental lithium, and that is equivalent to 21.75 kg of Lithium Carbonate (LCE) which is how Lithium comes out of the ground and how resources are evaluated.</p>
<p>So since 4.08kg of pure (elemental) lithium is equivalent to about 21.75kg of LCE (5.33kg of LCE is 1kg of Lithium). This means that the 24kWh battery contains 21.75kg of LCE, or about 0.9kg of LCE per kWh. This is 50% larger than the 0.6kg I had seen others cite as a figure for LCE per kWh, which would diminish the amount of batteries my in my estimates by 33%. But it seems there still will be plenty of LCE to go around since the numbers before were absurdly high.</p>
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		<title>Lithium Supplies &#8211; Locked and Loaded</title>
		<link>http://www.sequence-omega.net/2010/05/20/lithium-supplies-locked-and-loaded/</link>
		<comments>http://www.sequence-omega.net/2010/05/20/lithium-supplies-locked-and-loaded/#comments</comments>
		<pubDate>Fri, 21 May 2010 05:30:02 +0000</pubDate>
		<dc:creator>Anthony</dc:creator>
				<category><![CDATA[Batteries]]></category>
		<category><![CDATA[Electric Vehicles]]></category>
		<category><![CDATA[Hybrid Vehicles]]></category>
		<category><![CDATA[Range Extended Electric Vehicles]]></category>
		<category><![CDATA[lithium carbonate]]></category>
		<category><![CDATA[peak lithium]]></category>

		<guid isPermaLink="false">http://www.sequence-omega.net/?p=1059</guid>
		<description><![CDATA[While some have asked where we&#8217;re going to get Lithium for the next generation of Lithium-Ion batteries for cars, others are actually mining for Lithium. Western Lithium of Canada (WLC) has announced their Kings Valley Nevada site has twice the amount of Lithium in their stage II lens as previously expected. WLC, in a recent [...]]]></description>
			<content:encoded><![CDATA[<p>While some have asked where we&#8217;re going to get Lithium for the next generation of Lithium-Ion batteries for cars, others are actually mining for Lithium. Western Lithium of Canada (WLC) has announced their Kings Valley Nevada site has twice the amount of Lithium in their stage II lens as previously expected.</p>
<p><span id="more-1059"></span>WLC, in a recent <a href="http://www.westernlithium.com/news-items/4547">press release</a>, also stated that their target for their stage I lens production is 27,700 metric tonnes per year of Lithium Carbonate (LCE, or chemically Li2CO3). The math to turn that into the number of EVs is easy &#8211; 27,700 metric tonnes is 27,700,000 kg of LCE. In 1kWh of a Lithium-Ion battery there is 0.6kg <a href="http://www.sequence-omega.net/2010/05/27/lithium-math-quick-update/">0.9kg of LCE</a> (figures in this article have been updated). This means that 27.7M kg of LCE per year is about 30.8M kWh of batteries that can be produced. They have an expected 18 years at this rate of supply to mine (approximately 500,000 metric tonnes LCE total).</p>
<p>In a pure EV (like the Nissan Leaf) the battery is 24kWh, so from 27,700 tonnes of LCE comes 1.28M Nissan Leaf battery packs per year. In a EREV like the Chevy Volt, its battery pack is 16kWh, so 1.9M battery packs would be able to be manufactured for the Volt.</p>
<p>To put these numbers in perspective, in 2009 there were a total of 10.4M cars sold in the US, and in 2008 approximately 13M cars sold. So this single lithium mine could power up to 15% of all the US EVs and EREVs sold, if the automakers could build and sell that many (which they wont, at least initially).</p>
<p>So the question is, how many tonnes of LCE would it take to make every car sold in America a plug-in? From a small two-mode system that would allow for 8-12kWh batteries for 10-15 miles at speeds below 60MPH, all the way up to pure EVs with 50kWh batteries. If we assume that 70% of cars sold are two-mode at 10kW, 20% are EREV (18kWh) and the last 10% are pure EVs (35kWh avg), the total kWh for a year of 14M cars is 197.4M kWh, or 177.3M kg of LCE. So in order to produce enough LCE, we would need to produce about 180,000 metric tonnes of LCE, or about 6.5x the amount of stage I.</p>
<p>The stage II lens has approximately 1.365M tonnes of LCE, and at 180,000 metric tonnes per year, it would be exhausted after 7.5 years, assuming the production rate could be sustained.</p>
<p>Seven and a half years might not be a long time, however there are still several other stages to this mine area (stages three and four), plus there are other lithium mines in the Nevada and the US. It appears that Lithium supplies wont be a blockade on the road to electric cars. While Li-Ion batteries can also contain other precious metals that might be scarce, Lithium shouldn&#8217;t be an issue.</p>
<p>[Update 5/27 - updated Lithium math based on Leaf's use of 0.9kg/kWh]</p>
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		<item>
		<title>Lithium Carbonate Supplies Abound!</title>
		<link>http://www.sequence-omega.net/2009/05/15/lithium-carbonate-supplies-abound/</link>
		<comments>http://www.sequence-omega.net/2009/05/15/lithium-carbonate-supplies-abound/#comments</comments>
		<pubDate>Sat, 16 May 2009 04:26:36 +0000</pubDate>
		<dc:creator>Anthony</dc:creator>
				<category><![CDATA[Batteries]]></category>
		<category><![CDATA[Electric Vehicles]]></category>
		<category><![CDATA[Range Extended Electric Vehicles]]></category>
		<category><![CDATA[li2co3]]></category>
		<category><![CDATA[lithium]]></category>
		<category><![CDATA[lithium carbonate]]></category>
		<category><![CDATA[peak lithium]]></category>

		<guid isPermaLink="false">http://www.sequence-omega.net/?p=331</guid>
		<description><![CDATA[One of the worries I often hear about opposition to electric cars is that we&#8217;re trading one resource for another &#8211; oil for lithium. The list of countries with large lithium deposits aren&#8217;t overtly hostile to the US and its allies, however they are further left than we are (but who isn&#8217;t really?). Evo Morales [...]]]></description>
			<content:encoded><![CDATA[<p>One of the worries I often hear about opposition to electric cars is that we&#8217;re trading one resource for another &#8211; oil for lithium. The list of countries with large lithium deposits aren&#8217;t overtly hostile to the US and its allies, however they are further left than we are (but who isn&#8217;t really?). Evo Morales of Bolivia has already stated he didn&#8217;t want outside companies to come in to Bolivia and take the lithium. But do we have enough from other sources to provide the number of lithium-ion batteries we&#8217;ll need to power the cars of the future?</p>
<p><span id="more-331"></span>An article at Seeking Alpha discusses a <a href="http://seekingalpha.com/article/134838-lithium-supply-enough-to-cover-demands">lithium conference held in Chile</a> this year. At this conference, the future of lithium demands and reserves were discussed. The geologist who authored the article estimates that there are 30M tonnes of elemental lithium and 160M tonnes of carbonate (Li2CO3) &#8211; the actual material used in the production of lithium ion batteries.</p>
<p>Beyond that, there is a fairly high confidence of accuracy of these claims. Drilling performed in a mine along the Oregon/Nevada border indicated that an estimate from years ago was within 10% of a recent drilling. <a href="http://www.westernlithium.com/">Western Lithium</a> is focusing in on a single <a href="http://paguntaka.org/2008/04/02/western-uranium-corporation-provides-corporate-activity-update/">deposit of lithium of around 770,000</a> tonnes (1.5B lbs.) in Kings Valley, Nevada, with an estimated 11 million tonnes total (25B lbs.). With the recovery estimated at 85% for this area, that&#8217;s 9.35M tonnes of carbonate. They estimate producing 20,000 tonnes of LCE per year by 2013, and at a rate of 0.9kg/kWh of battery, it is enough for 3.4 million 6.5kWh battery packs per year (why 6.5kWh? thats about the right size for a 15-mile Prius plug-in). The most recent peak in the 1990s there were only 8.7M passenger cars sold (not including SUVs, trucks, etc), so a 6.5kWh battery coupled with sufficient technologies to allow 30 miles per day (2x charge/day; charge overnight, plus charge in the morning when you get to work) would allow 39% of cars manufactured to be PHEVs if the market and prices allowed, and this is just from one site located in northern Nevada, accessing only a fraction of what the site is expected to produce.</p>
<p>Down in southern Nevada near Tonapah, there is the only existing lithium brine recovery operation in the US in Clayton Valley, Nevada, where <a href="http://www.safehaven.com/article-13074.htm">estimates range from 2 million to 20 million tonnes</a> of LCE. One more valley over, there is the Fish Lake Valley, which has <a href="http://ca.news.finance.yahoo.com/s/16042009/28/link-f-ccnmatthews-tnr-gold-acquires-nevada-lithium-brine-properties.html">similar concentrations of lithium</a> as Clayton Valley. The Clayton Valley site currently produces 5,700 tonnes annually, or enough for about 594,000  16kWh battery packs per year &#8211; the first three or four years of Volt production wont exceed 250,000 units. <strong>And I still haven&#8217;t left the great state of Nevada</strong>.</p>
<p>The total amount of Lithium resources for just Nevada could be around 30-50M tonnes of LCE, or enough after recovery to build <strong>4.2 billion Prius Plug-ins, or 1.7 billion Chevy Volts</strong>. When you combine this with <a href="http://gm-volt.com/2010/11/08/gm-applies-for-patent-for-lithium-ion-battery-cell-refurbishing-system/">battery</a> and lithium recycling, the supplies are enough to last us well until we find the lithium-ion replacement technology.</p>
<p><strong>So what about recovery?</strong> Even by 2030 when plug-ins and pure electric cars are 90%+ of the sales (as Google.org estimates), that would mean an annual US vehicle production of 12 million vehicles per year would require almost 11M vehicle battery packs, at an average of 15kWh each, that&#8217;s 165 million kWh, or 99 million kg, or 99,000 tonnes just for the US. Worldwide, by 2020, its estimated that lithium-ion batteries for vehicles will require at most 70,000 tonnes per year, while various mining industry groups claim to be able to ramp to the high figures needed just themselves. This area appears to be well covered.</p>
<p>Finally is cost. Even at $250/kWh (the 2020 industry target price), lithium&#8217;s only about 2% of the battery price. The price for LCE is about $8/kg, or about $4.80/kWh, even doubling it doesn&#8217;t have a much of an effect on the price &#8211; from 2% to 4% of total cost in 2020.</p>
<p>We will still need to figure out what will come after lithium, though some companies are already <a href="http://www.autonews.com/apps/pbcs.dll/article?AID=/20080306/COPY/849670232/1186/emaildailyANE02">laying the groundwork for the post-lithium era</a>. But the doomsayers don&#8217;t have much of a leg to stand on, and we still haven&#8217;t got into <a href="http://www.osti.gov/energycitations/product.biblio.jsp?osti_id=7351225">harvesting lithium from seawater</a> (at a first-generation technology price of $22-32/kg, with enough lithium for 18 trillion Tesla Roaster battery packs).</p>
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